Moscow State University named after M.V. Lomonosov Faculty of VKNM
M. A. Yurovskaya, M. V. Livantsov, L. I. Livantsova, V. P. Dyadchenko
COLLECTION OF PROBLEMS ON ORGANIC CHEMISTRY
Moscow University Publishing House
BBK 24.2 Yu 78
3. Alcohols, alkyl halides, ethers, diols and epoxides. Nucleophilic substitution and elimination in aliphatic
row. Organometallic compounds | ||
Carbonyl compounds: aldehydes and ketones | ||
Carboxylic acids | ||
Aliphatic amines | ||
Aromatic amines, nitro- and diazo compounds | ||
Phenols and quinones | ||
Heterocyclic compounds | ||
10.Alicyclic compounds | ||
Introduction
This collection includes typical tasks By organic chemistry, offered to second-year students of the HCNM over the past 5 years in the ranking tests different levels, as well as in exam papers. The problems are classified in accordance with the main sections of the organic chemistry program.
The solution to most problems begins with a correct understanding of their conditions, which is completely impossible without knowledge of the basics of nomenclature organic compounds, which is one of the most important components of modern chemical language. Quite a lot of time is devoted to problems of the nomenclature of organic compounds in lectures and seminar classes, therefore in this collection there are no special tasks regarding nomenclature. At the same time, we strongly recommend that each student in the solution he proposes specific task be sure to give the names of all organic compounds mentioned in this problem according to systematic nomenclature(IUPAC nomenclature). The collection presents a large series of synthetic problems, in solving which it is necessary to use modern methods synthesis and reagents, as well as protecting groups that allow temporary (reversible) blocking of individual functional groups polyfunctional organic compounds.
Answering questions regarding mechanisms organic reactions, each student must be able to analyze data on: 1) kinetics; 2) stereochemistry; 3) the influence of the structure of the substrate and reagent; 4) the influence of the solvent; 5) the presence of a conjugate (competing) process; 6) use of labeled substrates or reagents; 7) the presence and nature of rearrangements during the reaction. For this purpose, all sections of the collection include analysis tasks various factors, affecting the characteristics of specific organic reactions.
Many problems are complex: their correct solution involves not only good knowledge students of reaction mechanisms, chemical properties and the main routes of synthesis of organic compounds, but also their understanding genetic connection between the main classes of organic compounds. In other words, each student must have the skills to conduct retrosynthetic analysis, on the basis of which the optimal route for the synthesis of a particular organic compound can be correctly planned.
1.ALIPHATIC HYDROCARBONS: ALKANES, ALKENES, ALKYNES, DIENES.
1. The energies of the C-H and C-C bonds in ethane are 98 kcal/mol and 88 kcal/mol, respectively. Explain why in radical processes occurring under not very harsh conditions, stronger ones are predominantly broken S-N connections? Which of the following possible reactions Is ethane with atomic chlorine actually realized? Give reasons for your answer in detail. Required reference data: the C-Cl bond energy in methyl chloride is 81 kcal/mol, the C-Cl bond energy in ethyl chloride is
82 kcal/mol, and the H-Cl bond energy is 103 kcal/mol.
CH3 CH2 | |||||
CH3 CH3 + Cl | CH3 CH2 Cl | ||||
CH3Cl+ | |||||
2. Hexachloroethane is produced in industry according to the following scheme:
2CH4 + 7Cl2 | CCl3 CCl3 | ||
Suggest a mechanism for this reaction.
3. Chlorination of hydrocarbons with trichloromethane sulfonyl chloride proceeds according to the following scheme:
RCH3 + CCl3 SO2 Cl | t 0 C | ||||
Write the most probable stages of development and circuit breakage.
4. Give the energy profile of rotation around the bond C2 -C3 ext - butane (change schedule potential energy molecules depending on size dihedral angle). What conformations of the n-butane molecule correspond to the minimums and maximums on this graph?
5. Which points on the graph below change the potential energy of a molecule? 1-bromo-2-chloroethane, depending on the dihedral angle, can correspond to conformations A, B and C?
BrCl | ClH | |||||||
6. Which of the following compounds corresponds to the energy profile of rotation around the bond? C-C (highlighted):
1. CH3 − CH2 CH3 | ||||
2. BrCH2 − CH3 | ||||
3. CH3 CH2 − CH2 CH3 | ||||
4. CH3 -CH2 CH2 CH3 | ||||
5. CH3 CHBr− CH3 | ||||
6. Br CH2 − CH2 CH3 * | ||||
7. Relative reactivity of primary, secondary and tertiary The CH bond ratio in radical bromination reactions is 1:32:1600, respectively. What will be the percentage composition of the radical monobromination products of isopentane in this case?*
8. In the presence of 60% sulfuric acid (700 C), isobutylene is converted into a mixture of isomeric octenes, which under catalytic hydrogenation conditions give the same branched saturated hydrocarbon- 2,2,4-trimethylpentane ( technical name“isooctane”). What isomeric octenes? we're talking about? Give the mechanism of their formation. Another industrial method The synthesis of “isooctane” (2,2,4-trimethylpentane) is based on the following reaction:
H SO conc., 00 C |
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(CH3 )2 C=CH2 | + (CH3 )3 CH | (CH3 )2 CHCH2 C(CH3 )3 |
||
or gaseous HF, |
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tracesH2 O, 00 C
Suggest a mechanism for this reaction.* 9. Explain the following reaction and suggest a mechanism for the process:
(CH3 )2 C=CH2 + CH2 =CH2 + HCl(CH3 )3 CCH2 CH2 Cl
10. Explain why isobutane, containing traces of isobutylene, is converted into nonadeuteroisobutane (CD3)3 CH when exposed to excess deuterosulfuric acid (D2 SO4)? *
11. By dehydration of 2,2-dimethylcyclohexanol in an acidic environment, two substances were obtained: isopropylidenecyclopentane and 1,2-dimethylcyclohexene. Suggest a mechanism for the formation of both substances
V specified conditions. How to transform the last substance in two stages
V 1,2-bis(hydroxymethyl)benzene? *
12. Dehydration of 3,3-dimethylbutanol-2 in the presence of phosphoric acid when heated leads to the following result:
(CH3)3C | H3PO4 | ||||||||
CH2 =CHC(CH3 )3 |
|||||||||
CH2=C |
|||||||||
CH(CH3)2 |
|||||||||
Explain this result.
13. It is known that when sodium ethoxide in ethanol reacts with erythro-2-bromo-3-deuterobutane, only two alkenes (E)-butene-2 and (Z)-2-deuterobutene-2 are formed. What mechanism is this result consistent with? Give Fischer formulas, wedge-shaped projections and Newman projections for both enantiomers of the starting erythro-2-bromo-3-deuterobutane. Give R, S designations for asymmetric centers.*
14. What compounds are formed when joining: a) hydrogen chloride, b) bromine in methanol to the following compounds:
1) CF3 CH=CH2, 2) CH2 =CHOCH3?
15. When hexen-5-ol-2 was treated with a solution of bromine in CCl4, a compound with the composition C6 H11 BrO was formed. What structure does this compound have? Give the mechanism of its formation.*
16. What products are obtained by adding HBr to the following compounds: a) CF3 CH2 CH=CH2, b) NO2 CH=CHCH3, c) ClCH=CH-CH3, d) CH2 =CHBr, e) CH2 =CHN+ (CH3)3 Cl− ?
17. Explain the mechanism of the following reaction:
CH3 СH(OCH3)CHClCH2 CH3 (50%)
CH3 CH=CHCH2 CH3 | CH3 СHClCH(OCH3)CH2 CH3 | |||
CH3 OH ex. |
||||
CH3 СHClCHClCH2 CH3 |
18. Arrange the following substrates in order of increasing reactivity in the reaction with hydrogen bromide: a) butene-2, 2-methylbutene-2, 2-chlorobutene-2, 2,3-dimethylbutene-2-oic acid, butene-1 . b) cyclohexene, 1-bromocyclohexene, 1-nitrocyclohexene, 1-methylcyclohexene, 1-methoxycyclohexene. Justify your answer. For each of the possible carbocations, indicate the stabilization factors and
destabilization. * | ||
19. What will be the result of the interaction? | (taking into account stereochemistry; |
|
wedge-shaped projections; R, S-notations for asymmetric |
||
centers): a) (Z)-3-methylpentene-2, b) (E)-3-methylpentene-2, c) 2- |
||
methylbutene-1, | d) methylenecyclohexane, | e) 1-methylcyclohexene, |
e) vinylcyclohexane with the following reagents: 1) H3 O+, 2) B2 D6, |
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CH3 COOH, 3) ICl, | 4) KMnO4 (pH 7, 200 C), 5) O3, oxidizing |
|
decomposition | ozonides, 6) O3, | restorative | decomposition |
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ozonides, 7) B2 H6, | 7) CH3COOD, | 8) Br2, in excess CH3 OH, 9) D2 in |
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presence | 10) Hg(OAc)2 | in ethanol, then | NaBD4/NaOD, |
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11) CF3 COOOH, 12) OsO4, then | NaHSO3 /H2 O, 13) NH=NH, 14) Br2 in |
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dioxane in the presence of an excess of labeled LiBr*, 15) CH2 N2, hν in the liquid phase (singlet carbene), 16) CH2 N2, hν in the gas phase in an argon atmosphere (triplet carbene), 17) HBr (dry), 18) HBr ( dry)
in the presence of ROOR (t 0 C).
20. Write the reaction products of cyclohexylacetylene (taking into account stereochemistry where necessary) with the following reagents: 1) Hg 2+ , H3 O+ , 2) D2 in the presence of Lindlar catalyst (Pd/BaSO4, deactivated with quinoline), 3) BuLi (1 equiv.), CH3 I, 4) RMgBr, D2 O, 5) (Sia)2 BH, then CH3 COOD, 6) D-9-BBN, then CH3 COOH, 7) LiNH2, then D2 O, 7) (Sia)2 BH, then CH3 COOD, 8) HBr (1 eq.), 9) HBr (1 eq. .) in the presence of ROOR, 10) O2, CuCl, pyridine, 11) NaOBr/H2 O, dark -
hexylacetylene, CuCl in pyridine. *
21. Write the reaction products of hexine-3 (taking into account stereochemistry, where necessary) with the following reagents: 1) H2, in the presence of a Lindlar catalyst (Pd/BaSO4, deactivated with quinoline),
then CF3 COOOH, 2) Br2 (1 eq.) in CCl4, 3) Na/NH3 (liquid), then CF3 COOOH, 4) B2 H6 (1 eq.), then CH3 COOD, 5) HCl (1 eq. gas ), 6) LiNH(CH2 )2 NH2 (LEDA – lithium ethylenediamide) in NH2 (CH2 )2 NH2 ,t 0 C,
then D2 O.*
22. Write the reactions of 2-methylbutadiene-1,3 with the following reagents:
1) HBr (1 eq.) in CCl4, 500 C, 2) HBr (1 eq.) in CCl4, -300 C, 3) HBr, ROOR, 500 C, 4) O3 (2 eq.), oxidative decomposition ozonides, 5) O3 (2 equiv.),
reductive decomposition | ozonides, | 6) diethyl | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
maleic (cis-butenedioic) | acids, t 0 C 7) diethyl | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
fumaric (trans-butenedioic) acid, | t 0 C, | 8) maleic |
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anhydride, t 0 C, | 9) diethyl | acetylene dicarboxylic acid ester, |
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t 0 C, 10) p-benzoquinone, t 0 C. | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
from the above | connections | react with |
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maleic anhydride? | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
C(CH3)3 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
(CH3)3C | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
1 trans-pentadiene-1,3 in the Diels-Alder reaction is comparable to reactivity butadiene-1,3, and cis-pentadiene-1,3 reacts much more slowly than butadiene-1,3. * 25. Receive by reaction Diels-Alder compounds*:
26. Based on propine-1 and other necessary reagents, obtain: a) 2-bromo-2-chloropropane, b) 1-bromo-2-chloropropane, c) 1-bromo-3-chloropropane, d) 2-bromo-1 -chloropropane. Give conditions and mechanisms of reactions.* 27. Based on propane, you get 1-bromo-3-iodo-2-chloropropane by three-step synthesis. 28. Propose a synthesis scheme mono-, 1,2-di- and 1,2,3-trideuterocyclohexanes, based on cyclohexene and any inorganic reagents.* 29. From methylenecyclopentane and other necessary reagents get 1-(deuteromethyl)cyclopentene-1. 30. Suggest the most appropriate synthesis route 1,2-dibromo-3-deuteropropane from available reagents. Give the conditions and mechanisms of the processes. 31. Starting from propane, obtain 1-bromo-3-deutero-2-methoxypropane by a four-step synthesis. 32. From acetylene through the same unsaturated compound C 4 H8 or C4 H6 get methyl ethyl ketone and butanal. 33. Suggest a method of receiving cyclohexadiene-1,3 from cyclohexane and other necessary reagents. What structure will the adduct of cyclohexadiene-1,3 with maleic anhydride have? 34. From acetylene and other necessary reagents you will obtain trans - icis - hexenes-3. What will be the stereochemical result of the interaction? these connections with aqueous solution KMnO4 at room temperature. 35. Suggest a synthesis method 4,5-bis(methoxycarbonyl)cyclopentane-1,3-dicarboxylic acid CH3 OOCCOOH CH3 OOCCOOH from cyclopentadiene and maleic acid dimethyl ester. Discuss the stereochemistry of the products from each step of your proposed synthesis. 36. An alkene produces only propionaldehyde during ozonolysis. Determine the structure of the alkene if it is known that upon processing neutral solution KMnO 4 it gives D,L-glycol. * 37. Suggest a method of synthesis ( Z)- and (E)-isomers of 1-deuterohexene-1, starting from acetylene. Any necessary reagents may be used.* 38. Predict the distribution of the isotopic label in the bromination products of labeled cyclohexene (atom 13 C is isolated in the cyclohexene molecule with an asterisk) using N-bromosuccinimide (NBS). 39. Explain the result of chlorination:
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Yakov Mikhailovich Yurovsky(real name and patronymic Yankel Khaimovich 7 (June 19), Kainsk Tomsk province - August 2, Moscow) - Russian revolutionary, Soviet party and statesman, security officer. The immediate leader of the execution of the latter Russian Emperor Nicholas II and his family.
Biography
early years
Revolutionary activities
TO revolutionary activities joined in 1905 in Tomsk. According to some indirect data, first he participated in the military organizations of the Bund, and then, following the example of Sverdlov (his close friend), joined the Bolsheviks. He was engaged in the dissemination of Marxist literature, and after the failure of the underground printing house he was forced to leave Russia and settled in Berlin, where, together with his entire family (wife Maria Yakovlevna, three children), he converted to Lutheranism. In 1912, he returned to Russia illegally, but was tracked down by security department agents and arrested. He was expelled from Tomsk for “harmful activities” with permission to choose his place of residence. So he ended up in Yekaterinburg, where he started a watch workshop and photography, and, as he describes it, “he was in full view of the gendarmes and the police, where they often dragged me,” and “the gendarmerie found fault with him,” forcing him to take photographs of suspicious persons and prisoners. Nevertheless, his workshop was simultaneously a headquarters for the Bolsheviks and a laboratory for the production of passports for them. In 1916, he was called to serve as a paramedic at a local hospital. So Yurovsky became an active agitator among the soldiers and after February Revolution sold his photo workshop, and with the proceeds he organized the Bolshevik printing house "Ural Worker", became a member of the Council of Workers' and Soldiers' Deputies, a prominent Bolshevik and one of the main leaders of the revolution in the Urals.
As he told in January 1934 at a meeting of participants revolutionary events, in April 1917, Sverdlov came to Yekaterinburg from the Bolshevik Central Committee and began organizing delegates to All-Russian conference(it took place on April 24 and at it Lenin announced a plan for the transition to socialist revolution). At the same time, Sverdlov, attracting the personnel he trained here, was preparing an alternative coup in the Urals - in case there was a failure in St. Petersburg, "beki" will take revenge in the Urals. Aron Solts did the same in Tyumen, Samuil Zwilling in Chelyabinsk, and so on. Under the Ural Council, a Military Department was organized for this purpose, headed by Filipp Goloshchekin sent by Sverdlov, and Yurovsky became his deputy. To arm the workers, they confiscated weapons from trains going to the front. During the October Revolution, the Military Revolutionary Committee was organized, which included Vayner, Krestinsky, Voikov, Branitsky, Yurovsky, as well as some anarchists and left Socialist Revolutionaries. Soon this Military Revolutionary Committee transferred power to the Ural Council. At the end of November, re-elections to the Ural Council were held (led by Yurovsky and Khokhryakov), as a result of which the majority of the council turned out to be supporters of the Bolsheviks, and soon Pavel Bykov was elected chairman of the Council, former member Petersburg Military Revolutionary Committee. In October, Bykov organized the shelling of the Winter Palace from the Peter and Paul Fortress and participated in its assault, led operations to suppress the uprising of the cadets, was elected to the Central Executive Committee at the Second Congress of Soviets, and then went to the Urals with the mandate of a representative of the central government, which Sverdlov gave him - to replace Chairman of the Ural Council Sosnovsky, who refused this honor.
Having established its power, the Ural Council immediately imposed an indemnity of 10 million rubles on the rich and factory owners to maintain their power, and in response to the sabotage of the bourgeoisie, it announced the transfer of plant management to the control of workers' committees. This was first carried out at the Nadezhda plant, which the Ural Bolsheviks proudly reported to Lenin, who received their delegation on December 5 and approved their actions. On December 7, at the Commissariat of Labor, they were given the first-ever act on the transfer of plant management to a collective of workers, and on December 9, the Council of People’s Commissars issued a decree “On confiscation and declaration of property Russian Republic all property of the joint-stock company of the Bogoslovsky Mining Society.” And they took a subscription from the Urals themselves with an obligation to diligently preserve proletarian property and increase labor productivity...
But the seizure of the factories did not bring dividends to the Bolsheviks (then, in 1925, many of them were transferred to the concession of the English company Lena Goldfields and other companies), and when Lenin was forced to conclude the Treaty of Brest-Litovsk, the Ural Council announced that it did not recognize the decision of the central government and announces revolutionary war Germany. The nationalization of banks was announced and carried out, and to ensure the military operations of the Ural Council against the Germans, beki began searching for hidden valuables. Yurovsky was then a Member of the Board of the Regional Cheka and Chairman of the Investigative Commission of the Revolutionary Tribunal; he and Khokhryakov with detachments of Red Guards went to the houses of the rich and took away valuables for revolutionary struggle with Germany. All this was taken as if for storage in national bank and was handed over to the Commissioner of the State Bank Voikov.
Bykov writes in his memoirs that he had a connection with Sverdlov, and he, with the threat of the city being captured by Kolchak’s men, “resolved the issue without a formal people’s court, proposing to shoot Romanov in Yekaterinburg.” Previously, he and Goloshchekin organized the transfer of the Romanovs to Yekaterinburg, and Yurovsky was appointed commandant of the house where the royal family was kept. Yurovsky writes that on July 16 a telegram was received to conventional language, containing an order to exterminate the Romanovs, and Pyotr Ermakov (chief of security at the special purpose house) writes that the directive from the center to shoot the Tsar (but not the Tsar’s family) was signed by Sverdlov, and the Ural Council, influenced by the opinion of the workers, decided to shoot everyone. Goloshchekin and Solovyov (Military Commissars and Commissioners of Justice Ural region) at 6 pm they ordered Yurovsky to carry out the order. Yurovsky claims that he personally shot Romanov with his Mauser, other participants (Ermakov, Medvedev, and some Magyars) shot the rest, and bayoneted those who were not killed. In total, they killed 12 people, including servants and family doctor Botkin. The destruction of the corpses was entrusted to Ermakov, but Yurovsky allegedly did not trust him, considering him sloppy, and decided to also participate. It can be assumed that through the Tsarina’s personal jeweler Rabinovich (who had access to her through Rasputin), Yurovsky, a jeweler himself, somehow knew that the Tsarina was buying diamonds and wanted to find them. They threw the bodies of the dead into an abandoned mine, and a day later they returned and began to burn them with acid and fire, trying to destroy any possibility of leaving any relics. At the same time, as Ermakov writes, it was discovered that diamonds were sewn into the clothes of the princesses - with a total weight of about half a pound...
Although at the same time they sent a train with the valuables of the State Bank to Moscow, Yurovsky writes about the diamonds found on the bodies of the princesses that all this “was buried in the Alapaevsky plant, in one of the houses in the underground, in 1919 it was dug up and brought to Moscow.” However, in the inventory of values royal family only fur coats, silver cutlery, icons in silver frames, and similar things are described, but diamonds do not appear, and their true fate is unknown...
Alleged portrait of Ya. Yurovsky, supposedly attributed to the brush of K. Malevich, private collection
They sent other valuables stored in the State Bank by train to Moscow via Perm, and Yurovsky fled from the White Guards on the second train with party archives. A participant in the removal of valuables, Semyon Glukhikh, a member of the control board at the regional commissariat of finance (he was also a guard of the Romanovs), writes that they were carrying gold, platinum and banknotes worth 100 million rubles, minted in chromo-lithography by the Bolsheviks (he calls them banknotes of the Ural region ), and they surrendered all this in Perm, since the path to Moscow was then blocked due to the Socialist Revolutionary uprising in Yaroslavl. Then it was all transported to Moscow.
The removal of Ural valuables caused outrage and an uprising in Yekaterinburg: a rally began at the Verkh-Isetsky plant (then a suburb of Yekaterinburg) under the slogans “Down with the commissars!”, “Long live constituent Assembly!”, at which they began to say that the Bolsheviks were robbing workers and leaving them without funds, they demanded the return of valuables, the release of hostages and the dissolution of the Red Guard. Goloshchekin and Yurovsky with a detachment of Red Guards and machine guns came to suppress them, and they, according to Alexander Medvedev, “were unarmed and could not respond.” The rebels were dispersed and shot. This was dealt with by a specially organized revolutionary tribunal, in which Yurovsky was a member and chairman of the investigative commission. Yurovsky does not report the number of his victims, but according to Medvedev, they “mercilessly shot everyone who showed anti-Soviet activity,” and “after that the city became quiet and the population took the position of ‘my hut is on the edge’...”
Execution of the royal family
Yakov Yurovsky went down in history as one of the main participants and leader of the execution of Nicholas II and his family.
There is a version that in order to carry out the execution, Yurovsky allegedly drew up a special document that included a list of the execution team. However, according to the results historical research I. F. Plotnikov can conclude that this document, at one time provided to the press by former Austrian prisoner of war I. P. Meyer, published in the USA in 1984 by E. E. Alferyev and, most likely, fabricated, does not reflect the real list participants in the execution.
On July 21, 1920, Yurovsky handed over the jewelry of the executed Romanov royal family to the commandant of the Moscow Kremlin P. D. Malkov.
Later years of life
On July 25, 1918, the Whites captured Yekaterinburg, Yurovsky moved to Moscow, where he became a member of the board of the Moscow Cheka and the head of the district Cheka. When the Bolsheviks returned to Yekaterinburg, he was appointed Chairman of the Ural Gubernia Cheka. He settled in the rich mansion of Agushevich - almost opposite the execution house. In 1921, he was sent to Gokhran to manage the gold department - to “bring in order and the liquid state of the valuables stored there.” Then Yurovsky was chairman of the trading department of the currency department of the People's Commissariat of Foreign Affairs, and in 1923 he became deputy director of the Krasny Bogatyr plant. Since 1928, he worked as director of the Polytechnic Museum in Moscow. He died in 1938 from a perforated duodenal ulcer.
Video on the topic
Family
Memory
In cinema
- - “The Kingslayer.” Malcolm McDowell plays Yurovsky.
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Area, m² 111
Moscow, Yurovskaya, metro Planernaya
Agent: Yuryeva Larisa Vladimirovna (+7-909-959-10-26). Lot No. 26048. Offer from the owner without COMMISSION. PSN on the 1st floor of a residential building 111 sq.m. Separate entrance from the street Power 23 kW. European-quality renovation. 3 air conditioners, forced exhaust, fire and security alarms, parking. The premises have been renovated and are ready to move in. Possibly for a salon, bank branch, personal services, store, etc. price 1 sq.m. : RUB 189,189
RUB 59,500,000 840,276 € 944,294 $
171,075 RUR/m² 2,415 €/m² 2,715 $/m²
Area, m² 347.8
Plot 2 acres.
For sale 4-level townhouse with land plot in the most ecologically clean area of Moscow - Kurkino. The main advantages of the area are good ecology, increased comfort of life, beautiful nature. The layout includes: 1st level: entrance hall-dressing room, electrical panel-storage room, maid's room, bathroom. Level 2: dining-living room with bay window, guest room, bathroom, exit to the courtyard. Level 3: master bedroom with access to the balcony, 2 children's bedrooms (one with a balcony), bathroom. Level 4, attic: office, room with dressing room, living room 30 m2, bathroom. All floors are united by a luxurious forged marble staircase. A total of 7 rooms, 4 bathrooms, 2 entrances to the house. The area adjacent to the house is 2 acres. All communications are central, air conditioning system, everything necessary for installation has been prepared bath complex. All roof windows are automatic with anti-burglar blinds and mosquito nets. The renovation was made from high-quality, imported materials. The house is fully furnished and ready to move in. Closed, guarded area with access control, children's playgrounds, walking areas, magnificent landscape design, very quiet. Nearby there is a stop for minibuses and buses to the metro stations "Planernaya" and "Rechnoy Vokzal". Nearby are the reserve “Valley of the River Skhodnya”, “Tushinsky”, the largest park in Moscow “Moskvoretsky”, “Serebryany Bor”. Ski slope with lift and recreation area, golf course. Developed infrastructure - new modern kindergarten, initial and new high school with swimming pools, clubs, shops "Magnolia" (24 hours a day), "Knacker", "Pyaterochka", consumer service salons, beauty salons, cafes, restaurants, banks - a 3-minute walk, clinics for children, adults, MFC, "Mega -Khimki" - 3 minutes by car, nearby - Outlet "Black Dirt", Hypermarket "Metro", "Auchan", "Ikea", "Obi", etc.
Area, m² 204
Moscow, Yurovskaya, 95, metro station Rechnoy Vokzal
Moscow, North-Western Administrative District, Yurovskaya street 95, metro station Rechnoy Vokzal, for sale PSN, total. pl. 204 sq.m., can be divided from 204 sq.m., 1/7 floor, Lot: 47462 BEST-Real Estate on Barrikadnaya, Agent Lyudmila, free-use non-residential premises for sale 203.9 sq.m., on the ground floor of a residential building in Kurkino, st. Yurovskaya, 95 (monolith-brick), fenced and guarded area, ceilings 3 meters, five rooms with a window (36, 30, 14, 12, 10 sq.m.), server room 9 sq.m., kitchen 8 sq.m. .m., there is a utility room, a shower, two bathrooms, two entrances.
Area, m² 348
Plot 2 acres.
Moscow, Yurovskaya, 94k4, metro Planernaya
Lot number: 2600159, Unique offer! Do you want to live in own home with the site, and continue to work in Moscow. Combine the romance of country life and maintain business activity. Then it's time to make your dream come true! 4-storey townhouse with a plot, located in cottage village"Aelita" of the Kurkino district is safety and comfort for you and your family. A premium class village is fresh air, forest park, squares, streams and the Skhodnya river. A highly developed infrastructure turns the village into a mini city. There are schools and a kindergarten, shops and cozy cafes. Fitness center, golf club, bike paths, restaurants and beauty salons, post office and medical center. TOWNHOUSE. The house has a European-quality designer renovation, using expensive materials, furniture and appliances. Wallpaper from Valentin Yudashkin. Warm floor. Unique chandeliers and sconces create a cozy atmosphere at home. Air conditioning on each floor with WI FI function. Comfortable layout: 1st FLOOR: entrance hall-dressing room, pantry, free room (accommodation for an au pair, gym, winter Garden), bathroom with preparation for installation of a spa complex. 2nd FLOOR: spacious kitchen-living room with dining area and bay window, fireplace - allowing you to admire the live fire. Guest bedroom, bathroom, spacious hall, access to a well-kept area and courtyard. 3rd FLOOR: bedroom with access to the balcony (a beautiful wrought-iron fence with a canopy), two bedrooms that can be used as children's rooms (one of them has a bay window with panoramic glazing), a bathroom equipped with a bathtub and a bidet. 4th FLOOR (attic): office, bedroom with dressing room, hall-living room, bathroom, laundry area with neatly laid out central communications. All floors are united by a luxurious marble staircase. Roof windows with electric drive, anti-burglary and sun-protection blinds, mosquito nets. The property has 2 parking spaces. Utility payments are the same as for an apartment in Moscow. One adult owner. Sale is free, without encumbrance. Quick access to a deal. Call. The townhouse is waiting for its owners!
66,160,500 RUR 934,338 € 1,050,000 $
119,151 RUR/m² 1,682 €/m² 1,891 $/m²
Area, m² 555 / 20
Plot 25 acres.
Moscow, Yurovskaya, 93 k24, metro Planernaya
House in Kurkino, microdistrict. 2 D. Layout: - ground floor: billiard room 35 m2, storage room 9 m2, storage room 8 m2, spa area with pool 65 m2, sauna 9 m2, bathroom 2 m2, technical underground; - 1st floor: entrance hall 8m2, hall 32m2, living room 35m2, kitchen 19m2, bathroom, guest room 15m2 with bathroom, garage for 2 cars 40m2, boiler room 11m2; - 2nd floor: hall 18m2, glazed terrace with panoramic glazing 62m2, bedroom 21m2 with bathroom with balcony 15m2, bedroom 16m2 with balcony, bedroom 15m2 with balcony, bedroom 12m2 with balcony, bathroom; -attic floor: 2 free rooms 80m2 with 5 households. blocks. A new Buderus gas boiler has been installed. Around the house nature protection zone, stream, forest, birdsong. The territory of the microdistrict is fenced, 24-hour security (security), entry by passes. Developed infrastructure of the area: within walking distance comprehensive school, kindergarten, bus stop public transport, fitness center, golf course, private educational institutions, 10 minutes away a large shopping center, 24-hour shops. AFY-502555432
500,000 rubles 7,061 € 7,935 $
Area, m² 650
Moscow, Yurovskaya, 92, metro station Rechnoy Vokzal
Moscow, North-Western Administrative District, Yurovskaya street 92, metro station Rechnoy Vokzal, for rent Shop, total. pl. 650 sq.m., can be divided from 105 sq.m., 1/10 floor, Don't miss this profitable chance! Free premises for rent in the Kurkino area on Yurovsky Street. The first floor of a multi-storey residential building, which is located in a fashionable quarter. 50kw. It is possible to increase the area up to 650 sq.m. There are many schools and kindergartens in the area and new ones are opening. At the same time, there is a clear shortage of children's institutions (clubs, sports sections, etc.). A bright and warm room is perfect for a children's club or studio. As an alternative - a medical center of any specialty, including dentistry. There are no competitors in the area!!! Prompt display, reasonable bargaining. Call us and we will tell you in detail about all the advantages of this property!
RUB 49,000,000 691,992 € 777,654 $
140,804 RUR/m² 1,988 €/m² 2,234 $/m²
Area, m² 348
Plot 2 acres.
Moscow, Yurovskaya, 94k4, metro Planernaya
Lot number: 2611787, Unique offer! Do you want to live in your own house with a plot, and continue to work in Moscow. Combine the romance of country life and maintain business activity. Then it's time to make your dream come true! A 4-storey townhouse with a plot, located in the Aelita cottage village in the Kurkino district, is safety and comfort for you and your family. A premium class village has clean air, a forest park, public gardens, streams and the Skhodnya River. A highly developed infrastructure turns the village into a mini city. There are schools and a kindergarten, shops and cozy cafes. Fitness center, golf club, bike paths, restaurants and beauty salons, post office and medical center. TOWNHOUSE. The house has a European-quality designer renovation, using expensive materials, furniture and appliances. Wallpaper from Valentin Yudashkin. Warm floor. Unique chandeliers and sconces create a cozy atmosphere at home. Air conditioning on each floor with WI FI function. Comfortable layout: 1st FLOOR: entrance hall-dressing room, pantry, free room (accommodation for an au pair, gym, winter garden), bathroom with preparation for installing a SPA complex. 2nd FLOOR: spacious kitchen-living room with dining area and bay window, fireplace - allowing you to admire the live fire. Guest bedroom, bathroom, spacious hall, access to a well-kept area and courtyard. 3rd FLOOR: bedroom with access to the balcony (a beautiful wrought-iron fence with a canopy), two bedrooms that can be used as children's rooms (one of them has a bay window with panoramic glazing), a bathroom equipped with a bathtub and a bidet. 4th FLOOR (attic): office, bedroom with dressing room, hall-living room, bathroom, laundry area with neatly laid out central communications. All floors are united by a luxurious marble staircase. Roof windows with electric drive, anti-burglary and sun-protection blinds, mosquito nets. The property has 2 parking spaces. Utility payments are the same as for an apartment in Moscow. One adult owner. Sale is free, without encumbrance. Quick access to a deal. Bargain. Call. The townhouse is waiting for its owners!
RUB 35,500,000 501,341 € 563,402 $
174,019 RUR/m² 2,457 €/m² 2,761 $/m²
Area, m² 204
Moscow, Yurovskaya, 95, metro Planernaya
Moscow, North-Western Administrative District, Yurovskaya street 95, Planernaya metro station, for sale PSN, total. pl. 204 sq.m., can be divided from 204 sq.m., 1/7 floor, Lot: 47462 BEST-Real Estate on Barrikadnaya, Agent Lyudmila, free-use non-residential premises for sale 203.9 sq.m., on the ground floor of a residential building in Kurkino, st. Yurovskaya, 95 (monolith-brick), fenced and guarded area, ceilings 3 meters, five rooms with a window (36, 30, 14, 12, 10 sq.m.), server room 9 sq.m., kitchen 8 sq.m. .m., there is a utility room, a shower, two bathrooms, two entrances.
140,000,000 rubles 1,977,121 € 2,221,869 $
244,328 RUR/m² 3,450 €/m² 3,877 $/m²
Area, m² 573 / 17
Plot 15 acres.
Moscow, Yurovskaya, 93, metro Planernaya
Real estate agency Realty-Gorod offers to buy a mansion in Kurkino, Moscow. One of best offers on the real estate market! Moscow, Kurkino district. Own. A unique mansion with a total area of 573 sq. m. is offered for sale. m. with a land plot of 15 acres. The mansion is ready to move in: 3 floors + ground floor, built of brick, external walls are made of facing tiles. Metal roofing with quality system spillways, double-glazed windows, reinforced concrete ceilings. Ceiling height 3m. Communications are central. The decoration is made in a palace style using high-quality materials (marble, stucco, valuable wood). The house is made according to individual project, premium furniture and household appliances are available, the house is equipped with video surveillance, intrusion and fire alarms, and air conditioning. Utility payments, including security and cleaning of the territory, amount to 15,000 rubles. per month in summer time and up to 17,000 rubles. in winter. Adjacent area correct form with landscape design and lighting, coniferous trees planted, 2 fountains, alpine slides. A separate closed gazebo of 30 sq. m was built on the site. m for relaxation with a built-in kitchen and barbecue. The territory is guarded around the clock, entry is through a barrier. Solid environment. Illuminated streets. Park area. There is a golf club nearby. Floor description: Basement: billiard room, guest bedroom, bathroom, dressing room, laundry room, staff apartment with separate exit, boiler room, garage. 1st floor: entrance hall, dressing room, kitchen, dining room, living room, winter garden, 2 separate exits - to the garden and to the garage. 2nd floor: 2 bedrooms, office, library, 3 bathrooms, 2 bathrooms, 3 dressing rooms. 3rd floor: 2 bedrooms, bathroom, shower, games room. AFY-504601324
46,000 RUR 649 € 730 $
Area, m² 54 / 25 / 12
Moscow, Yurovskaya, 95 bldg. 1
401-4 Vladimir. One-room apartment for rent. Moscow, Yurovskaya street, building 95k1, floor 5/8, total area 54 sq.m., living area 25 sq.m., kitchen 12 sq.m., landline telephone, internet, elevator, all furniture, balcony, washing machine , refrigerator, TV. Price 46,000 rub. See photo. Wishes for residents: any composition will be considered - everyone. The house is warm and nice. Call. THE OFFER IS REAL. Bargaining is possible during viewing (COMMISSION DISCOUNT). The owner works only with me. Hurry up. Today we show. The display is operational. The owner is just a sweetheart, very decent. You can get to the apartment: 15 minutes by transport from Planernaya metro station. URGENTLY! Lot 53040
RUB 41,000,000 579,014 € 650,690 $
149,090 RUR/m² 2,105 €/m² 2,366 $/m²
Area, m² 275
Plot 2 acres.
Moscow, Yurovskaya, 93k7
B Townhouse 275 m on a plot of 2 acres. /b br/ Three-story townhouse in a guarded elite village just 3 km from the Moscow Ring Road. Fenced green area, entry and passage through checkpoints with passes, 24-hour security. 3 floors, 5 bedrooms with bathrooms, huge kitchen-living room, winter garden, sunny terrace overlooking the center of the village, garage for a car. The townhouse is fully equipped with the necessary furniture and appliances. In good livable condition. Quiet permanent neighbors, green area, developed infrastructure, at the entrance to the village there is a solid medical clinic. A 3-minute drive away is the shopping center MEGA-Khimki, Auchan, Obi, Ikea, Stockmann. Free sale, mortgage possible, full price in the contract.
Real estate agency "Realty-Gorod" offers to buy a townhouse in the Kurkino district of North-Western Administrative District of Moscow at the address: st. Yurovskaya, house 93, bldg. 5, near Planernaya metro station. The townhouse is located in a closed, guarded area with access control. It is very well located inside the village itself - not far from the exit (checkpoint) and at the same time far from the main roadway. Townhouse with a total area of 240 sq. m. m, consists of four levels. It has well-planned residential and auxiliary areas. On the ground floor there is a kitchen and a living room with access to a fenced private territory - a plot, a boiler room, an entrance hall, a bathroom, a utility room. block; on the second floor - a bedroom with its own shower, living room, dressing room, bathroom - bathroom, room for washing and ironing; on the third floor there are two living rooms, a bathroom - a bathroom. The fourth level is a residential attic. Bathrooms are equipped with all necessary plumbing. Townhouse renovated, furnished and equipped. In front of the townhouse there is a carport with a carport. Developed infrastructure: next to the residential village there is a kindergarten, a school, various shops, consumer service salons, beauty salons, cafes, restaurants, banks, and a medical clinic on the territory of the village. Close to residential complex there are hypermarkets Mega, Auchan, Ikea, Ob, a ski slope with a lift and a recreation area, a golf course, natural Park and the Skhodnya River floodplain reserve, very beautiful and scenic spots. good transport connection to Planernaya metro station, complete absence traffic jams, very convenient access to the Moscow Ring Road. Free sale. Owned for more than three years. One adult owner. AFY-503052366
Lot number: 2611706, Unique offer! Do you want to live in your own house with a plot, and continue to work in Moscow. Combine the romance of country life and maintain business activity. Then it's time to make your dream come true! A 4-storey townhouse with a plot, located in the Aelita cottage village in the Kurkino district, is safety and comfort for you and your family. A premium class village has clean air, a forest park, public gardens, streams and the Skhodnya River. A highly developed infrastructure turns the village into a mini city. There are schools and a kindergarten, shops and cozy cafes. Fitness center, golf club, bike paths, restaurants and beauty salons, post office and medical center. TOWNHOUSE. The house has a European-quality designer renovation, using expensive materials, furniture and appliances. Wallpaper from Valentin Yudashkin. Warm floor. Unique chandeliers and sconces create a cozy atmosphere at home. Air conditioning on each floor with WI FI function. Comfortable layout: 1st FLOOR: entrance hall-dressing room, pantry, free room (accommodation for an au pair, gym, winter garden), bathroom with preparation for installing a SPA complex. 2nd FLOOR: spacious kitchen-living room with dining area and bay window, fireplace - allowing you to admire the live fire. Guest bedroom, bathroom, spacious hall, access to a well-kept area and courtyard. 3rd FLOOR: bedroom with access to the balcony (a beautiful wrought-iron fence with a canopy), two bedrooms that can be used as children's rooms (one of them has a bay window with panoramic glazing), a bathroom equipped with a bathtub and a bidet. 4th FLOOR (attic): office, bedroom with dressing room, hall-living room, bathroom, laundry area with neatly laid out central communications. All floors are united by a luxurious marble staircase. Roof windows with electric drive, anti-burglary and sun-protection blinds, mosquito nets. The property has 2 parking spaces. Utility payments are the same as for an apartment in Moscow. One adult owner. Sale is free, without encumbrance. Quick access to a deal. Call. The townhouse is waiting for its owners!